General Properties and Industrial Significance:
EDTA-Cu(NH₄)₂ is a copper chelate, where copper (Cu²⁺) is bound to EDTA (ethylenediaminetetraacetic acid), and the complex is neutralized with two ammonium (NH₄⁺) ions. It is a water-soluble, stable form of copper, used in agricultural applications to provide copper to plants in a bioavailable form.
EDTA-Cu(NH₄)₂ is a copper fertilizer in which copper is chelated (or bound) by EDTA to maintain its solubility and bioavailability.
The ammonium ions (NH₄⁺) are used to balance the charge of the chelate and contribute a small nitrogen source for plant nutrition.
Applications:
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Agriculture:
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Copper deficiency correction: Used to treat or prevent copper deficiencies in plants, especially in crops like citrus, tomatoes, corn, soybeans, and ornamentals.
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Copper is essential for:
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Enzyme activation: Important in various metabolic processes.
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Chlorophyll production: Supports photosynthesis.
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Lignin synthesis: Important for strengthening plant cell walls.
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Reproductive development: Aids in flower and seed formation.
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Application Methods:
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Soil application: Directly applied to soil to provide copper in a plant-available form.
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Foliar sprays: Applied to leaves for quick uptake by plants.
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Fertigation: Delivered through irrigation systems to ensure even nutrient distribution.
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Hydroponics: Used in water-based growing systems where copper must remain soluble and available.
Key Benefits:
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Bioavailability:
The EDTA chelation keeps copper in a form that is easily absorbed by plants, even in slightly alkaline or neutral soils.
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Prevents copper lock-up:
In high pH or alkaline soils, where copper tends to become insoluble, EDTA helps maintain the copper in solution.
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Ammonium ions (NH₄⁺):
Besides balancing the charge, the ammonium also provides a small nitrogen source for plants, which can be beneficial for their overall growth.
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Effective in a variety of pH levels:
Especially useful in slightly acidic to neutral soils where copper may otherwise become unavailable to plants.
Summary:
EDTA-Cu(NH₄)₂ is a copper chelate fertilizer used to correct copper deficiencies in plants. The EDTA chelation ensures that copper remains soluble and available for plant uptake, and the ammonium ions (NH₄⁺) contribute to nitrogen nutrition. This form of copper is particularly effective in neutral to slightly alkaline soils where copper might become immobilized.